1.Introduction 2.Background i. PCB Structure, Composition, Uses, Properties - heterogeneous ii. Brief Overview of Current Practises - Flow diagram/words to describe process in general iii. Drivers a. Price - Precious metals is main driver due to high prices b. Resource Depletion c. Social Responsibility d. Increased disposal rates - [“The rapid innovation in technology has resulted in availability of cheaper and better electronic products in the market making products obsolete faster and shortening the product life”] e. Social Responsibility f. Legislation 3. PCB Recycling i. Pretreatment a. Composition Analysis - Techniques?? - Identify reusable parts - AAS, ICP-AES b. Disassembly/Dismantling - They use lasers and stuff - Reusable parts are shipped back to the market or OEM - Removal of hazardous components - Generally Manual (not economical) - Research into auto and semi auto (Austria full scale) ii. Separation/Concentration - Shredding and crushing to reduce particle size ( find the optimum size) - Separation methods o Size o Density o Electrostatic o Eddy (Al) o Magnetic o Gravitational iii. Refining/Recovering a. Hydrometallurgy - Most metals are recovered at high efficiency - Environmental impacts – effluents - Different Chemicals used at different stages o Fluoroboric acid for Solder o Sulphuric/Nitric for Copper o Cyanide for Gold (?)  Thiourea  Thiosulphate  Halides o Alternatives - For Metal/Non-Metal mixes use Leaching - For Metallic mixes use electrochemical processes b. Pyrometallurgy - Smelting to recover copper, tin and lead • waster generation: slag and ash, volume waste • environmental impacts: global warming, acidification, photochemical ozone creation, and eutrophication • resource draw: lignite, natural gas, crude oil, coal, aluminum, iron, and zinc - Air Pollution - Flame retardant properties of matrix - Potential use of oil and gas effluents for fuelling system What about substrate? Ceramics, Glass, Polymers! Out of scope?